• 文献标题:   Fabrication and characterization of magnetite/reduced graphene oxide composite incurred from iron ore tailings for high performance application
  • 文献类型:   Article
  • 作  者:   MUTHUKANNAN V, PRAVEEN K, NATESAN B
  • 作者关键词:   magnetic material, chemical synthesi, electrochemical technique, xray photoemission spectroscopy xps, electrochemical propertie
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   Anna Univ
  • 被引频次:   9
  • DOI:   10.1016/j.matchemphys.2015.06.006
  • 出版年:   2015

▎ 摘  要

A feasible approach to synthesis iron oxide (Fe3O4) from waste iron ore tailings (IOTs) to synthesis magnetic graphene (Fe3O4/rGO) is demonstrated in the present study. Plain Fe3O4 was prepared by acid leaching of IOTs with hydrochloric acid followed by co precipitation. The anchoring of Fe3O4 onto the graphene template was done by hydrothermal method involving polyvinylpyrollidone (PVP) as a surface directing agent. The samples were characterized by FTIR, XRD, SEM, TEM, Nitrogen adsorption -desorption studies, XPS and Raman spectroscopic analysis. The electrochemical performances of the material were evaluated by cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge discharge techniques. The synergistic effect between the rGO matrix and Fe3O4 directs to increased conductivity and ionic diffusion, leading to a material with superior electrochemical performance. Thus the synthesis of magnetic graphene composite from IOTs was technically feasible, providing additional opportunities for future application of these composites in environmental management. (C) 2015 Elsevier B.V. All rights reserved.