• 文献标题:   Epoxidation of trans-stilbene with molecular oxygen over an eco-friendly heterogeneous cobalt oxide/reduced graphene oxide composite material
  • 文献类型:   Article
  • 作  者:   RANA S, VARADWAJ GBB, BHASKARUNI SVHS, JONNALAGADDA SB
  • 作者关键词:   reduced graphene oxide, cobalt, epoxidation, transstilbene, heterogeneous catalyst
  • 出版物名称:   RESEARCH ON CHEMICAL INTERMEDIATES
  • ISSN:   0922-6168 EI 1568-5675
  • 通讯作者地址:   Univ KwaZulu Natal
  • 被引频次:   0
  • DOI:   10.1007/s11164-020-04215-7 EA JUL 2020
  • 出版年:   2020

▎ 摘  要

We report the synthesis of 1, 5, 10 wt% cobalt oxide/reduced graphene oxide (CoO-RGO) composite materials by a simple solvothermal method. We assessed their catalytic activity in liquid phase epoxidation reaction without any sacrificial reductant and fully characterised the prepared catalysts by different techniques, including powder XRD, Raman spectra, scanning electron microscopy, transmission electron microscopy and ICP-MS. 5 wt% Cobalt oxide (CoO-RGO-5) promoted material showed high conversion (57%) of trans-stilbene oxide and excellent selectivity (96%) towards trans-stilbene epoxidation in DMF solvent by using the molecular oxygen as an oxidant. The conversion efficiency of trans-stilbene reaction remained the same for fresh and recycled catalysts after the 4th run.