• 文献标题:   Synthesis and Characterization of Red-Luminescent Graphene Oxide Functionalized with Silica-Coated Eu3+ Complex Nanoparticles
  • 文献类型:   Article
  • 作  者:   ZHAO C, FENG LY, XU BL, REN JS, QU XG
  • 作者关键词:   europium, graphene, luminescence, nanoparticle, rare earth
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539 EI 1521-3765
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   20
  • DOI:   10.1002/chem.201003712
  • 出版年:   2011

▎ 摘  要

Traditional dye-doped fluorescent graphene oxide (GO) reveals a low quantum yield and a short life expectancy. Herein, red-luminescent silica-coated Eu3+ complex nanoparticles were synthesized and covalently coupled to GO nanosheets by means of a carbodiimide-mediated amidation process. SEM and TEM studies demonstrated successful attachment of the silica-coated Eu3+ complex nanoparticles onto the GO surface. Spectroscopic studies showed that the GO-nanoparticle conjugates exhibit strong luminescence, long lifetimes, as well as good photostability, which suggests that this new type of luminescent nanomaterial has the potential for highly sensitive time-resolved fluorescence cyto- and histochemistry imaging.