• 文献标题:   Facile synthesis of porous graphene-like carbon nitride (C6N9H3) with excellent photocatalytic activity for NO removal
  • 文献类型:   Article
  • 作  者:   DONG GH, HO WK, LI YH, ZHANG LZ
  • 作者关键词:   porou, c6n9h3, photocatalytic, no removal, visible light
  • 出版物名称:   APPLIED CATALYSIS BENVIRONMENTAL
  • ISSN:   0926-3373 EI 1873-3883
  • 通讯作者地址:   Hong Kong Inst Educ
  • 被引频次:   91
  • DOI:   10.1016/j.apcatb.2015.03.035
  • 出版年:   2015

▎ 摘  要

We reported the possible synthesis of a new porous graphene-like carbon nitride (C6N9H3) by simply adding hydrochloric acid in the precursor of block g-C3N4. The formation of the porous graphene-like C6N9H3 can be attributed to the change in the thermal condensation modal of the precursor and the acidic condition induced by Cl- and H+. The photocatalytic activity of the samples was evaluated by the removal of NO under visible light illumination. We found that the porous graphene-like C6N9H3 exhibited enhanced photocatalytic activity compared to the block g-C3N4. We also researched the removal mechanism and found that the removal of NO in our systems was due to the synergic effect of h(+) and O-center dot(2-). This study could shed light on the design of efficient photocatalysts and facilitate a deep understanding of the NO removal mechanism through photocatalytic technology. (C) 2015 Elsevier B.V. All rights reserved.