▎ 摘　　要

Hierarchical three-dimensional graphene-based carbon materials have been successfully prepared via a template-assisted approach. It is found that the structure, morphology, graphitization degree, surface area and pore volume for the obtained carbon materials could be easily controlled by adjusting the amount of reactant and template. The results show that the obtained hierarchical nanostructured carbon material possesses a very stable reversible capacity of 395 mAh g(-1) at 1C and exhibits extremely high reversible capacity of 163 mAh g(-1) at the high rate of 20C. The large macroporous network and small mesopores in the materials can facilitate electrolyte and lithium ion transportation. The hollow carbon nanoparticles composed of stacked graphene can favor the electron diffusion within the materials. The micropores in the carbon materials can also increase the reversible capacity.