• 文献标题:   Electricity Recovery from Municipal Sewage Wastewater Using a Hydrogel Complex Composed of Microbially Reduced Graphene Oxide and Sludge
  • 文献类型:   Article
  • 作  者:   YOSHIDA N, MIYATA Y, MUGITA A, IIDA K
  • 作者关键词:   graphene oxide, municipal sewage wastewater, microbial fuel cell, geobacter, geothrix
  • 出版物名称:   MATERIALS
  • ISSN:   1996-1944
  • 通讯作者地址:   Nagoya Inst Technol
  • 被引频次:   8
  • DOI:   10.3390/ma9090742
  • 出版年:   2016

▎ 摘  要

Graphene oxide (GO) has recently been shown to be an excellent anode substrate for exoelectrogens. This study demonstrates the applicability of GO in recovering electricity from sewage wastewater. Anaerobic incubation of sludge with GO formed a hydrogel complex that embeds microbial cells via pi-pi stacking of microbially reduced GO. The rGO complex was electrically conductive (23 mS . cm(-1)) and immediately produced electricity in sewage wastewater under polarization at + 200 mV vs. Ag/AgCl. Higher and more stable production of electricity was observed with rGO complexes (179-310 mu A . cm(-3)) than with graphite felt (GF; 79-95 mu A . cm(3)). Electrochemical analyses revealed that this finding was attributable to the greater capacitance and smaller internal resistance of the rGO complex. Microbial community analysis showed abundances of Geobacter species in both rGO and GF complexes, whereas more diverse candidate exoelectrogens in the Desulfarculaceae family and Geothrix genus were particularly prominent in the rGO complex.