• 文献标题:   Manganese oxide nanoparticles supported on graphene oxide as an efficient nanocatalyst for the synthesis of 1,2,4-oxadiazoles from aldehydes
  • 文献类型:   Article
  • 作  者:   SAADATI F, KABOUDIN B, HASANLOEI R, NAMAZIFAR Z, MARSET X, GUILLENA G
  • 作者关键词:   1, 2, 4oxadiazole, graphene oxide, manganese dioxide, nanoparticle, oxidation
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Univ Zanjan
  • 被引频次:   0
  • DOI:   10.1002/aoc.5838 EA JUN 2020
  • 出版年:   2020

▎ 摘  要

The easy synthesis of graphene oxide (GO)-supported manganese dioxide (MnO2) nanoparticles as a stable heterogeneous nanocatalyst (MnO2@GO) is described. This catalyst was investigated in the synthesis of 1,2,4-oxadiazoles from amidoximes and aldehydes via a cyclization and oxidation process. The nanocomposite was prepared and characterized using various techniques. The catalytic application of the nanocomposite was examined in the reaction of a variety of aldehydes with aliphatic and aromatic amidoximes. The stable and robust catalyst was recycled for seven consecutive runs without a significant decrease in the catalytic activity.