• 文献标题:   Ti3C2Tx MXene-Reduced Graphene Oxide Composite Electrodes for Stretchable Supercapacitors
  • 文献类型:   Article
  • 作  者:   ZHOU YH, MALESKI K, ANASORI B, THOSTENSON JO, PANG YK, FENG YY, ZENG KX, PARKER CB, ZAUSCHER S, GOGOTSI Y, GLASS JT, CAO CY
  • 作者关键词:   stretchable supercapacitor, mxene, reduced graphene oxide, composite electrode, energy storage device, stretchable electrode
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Duke Univ
  • 被引频次:   14
  • DOI:   10.1021/acsnano.9b10066
  • 出版年:   2020

▎ 摘  要

The development of stretchable electronics requires the invention of compatible high-performance power sources, such as stretchable supercapacitors and batteries. In this work, two-dimensional (2D) titanium carbide (Ti(3)C(2)Tx) MXene is being explored for flexible and printed energy storage devices by fabrication of a robust, stretchable high-performance supercapacitor with reduced graphene oxide (RGO) to create a composite electrode. The Ti3C2Tx /RGO composite electrode combines the superior electrochemical and mechanical properties of Ti3C2Tx and the mechanical robustness of RGO resulting from strong nanosheet interactions, larger nanoflake size, and mechanical flexibility. It is found that the Ti3C2Tx/RGO composite electrodes with 50 wt % RGO incorporated prove to mitigate cracks generated under large strains. The composite electrodes exhibit a large capacitance of 49 mF/cm(2) (similar to 490 F/cm(3) and similar to 140 F/g) and good electrochemical and mechanical stability when subjected to cyclic uniaxial (300%) or biaxial (200% X 200%) strains. The as-assembled symmetric supercapacitor demonstrates a specific capacitance of 18.6 mF/cm(2) (similar to 90 F/cm(3) and similar to 29 F/g) and a stretchability of up to 300%. The developed approach offers an alternative strategy to fabricate stretchable MXene-based energy storage devices and can be extended to other members of the large MXene family.