• 文献标题:   Using 3-Isocyanatopropyltrimethoxysilane to Decorate Graphene Oxide with Nano-Titanium Dioxide for Enhancing the Anti-Corrosion Properties of Epoxy Coating
  • 文献类型:   Article
  • 作  者:   LI WH, SONG BJ, ZHANG SR, ZHANG F, LIU C, ZHANG N, YAO HL, SHI YC
  • 作者关键词:   graphene oxide, titanium dioxide, 3isocyanatopropyltrimethoxysilane, epoxy, modification, anticorrosion
  • 出版物名称:   POLYMERS
  • ISSN:  
  • 通讯作者地址:   Shandong Univ
  • 被引频次:   4
  • DOI:   10.3390/polym12040837
  • 出版年:   2020

▎ 摘  要

In this paper, the graphene oxide loaded with nano titanium dioxide (TiO2-GO) was synthesized through 3-isocyanatopropyltrimethoxysilane (IPTMS) and characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction analysis (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and dispersion test. The results illustrated our modification was successful and TiO2-GO was transferred from hydrophilic to hydrophobic. That greatly enhanced the dispersity of TiO2-GO in epoxy through the observation of the coating morphology test. Moreover, the impact of TiO2-GO on anti-corrosion property in epoxy was investigated by Electrochemical Impedance Spectroscopy (EIS). Comparing to pristine particles including GO and TiO2, TiO2-GO could more significantly improve the resistance of corrosion with the help of IPTMS. Furthermore, the anti-corrosion mechanism of TiO2-GO in epoxy was tentatively proposed and discussed.