• 文献标题:   Graphene electrochemistry: Surfactants inherent to graphene inhibit metal analysis
  • 文献类型:   Article
  • 作  者:   BROWNSON DAC, BANKS CE
  • 作者关键词:   graphene, surfactant, metal analysi, electron transfer, edge planelike sites/defect
  • 出版物名称:   ELECTROCHEMISTRY COMMUNICATIONS
  • ISSN:   1388-2481 EI 1873-1902
  • 通讯作者地址:   Manchester Metropolitan Univ
  • 被引频次:   63
  • DOI:   10.1016/j.elecom.2010.11.024
  • 出版年:   2011

▎ 摘  要

We demonstrate for well characterised and commercially available graphene that the surfactant used in its fabrication inhibits the electro-analytical sensing of cadmium(II) via anodic stripping voltammetry. Inspection of the deposition and stripping steps reveals that the surfactant inhibits the latter corresponding to the transition of cadmium metal to cadmium ions; this observation is in distinct contrast to the current electrochemical literature of graphene for metal analysis. (C) 2010 Elsevier B.V. All rights reserved.