• 文献标题:   Recyclable N-heterocyclic carbene/palladium catalyst on graphene oxide for the aqueous-phase Suzuki reaction
  • 文献类型:   Article
  • 作  者:   PARK JH, RAZA F, JEON SJ, KIM HI, KANG TW, YIM D, KIM JH
  • 作者关键词:   graphene oxide go, heterogeneous catalyst, palladium catalyst, suzuki reaction, nheterocyclic carbene nhc
  • 出版物名称:   TETRAHEDRON LETTERS
  • ISSN:   0040-4039
  • 通讯作者地址:   Hanyang Univ
  • 被引频次:   45
  • DOI:   10.1016/j.tetlet.2014.04.078
  • 出版年:   2014

▎ 摘  要

Graphene oxide (GO) was functionalized with a N-heterocyclic carbene (NHC) precursor, 3-(3-aminopropy1)-1-methylimidazolium bromide ([APMIm][Br]) for the immobilization of palladium catalyst. The GO-supported NHC precursor (IMGO) formed a stable complex with Pd(OAc)(2) (GO-NHC-Pd), which showed excellent catalytic activity and fast reaction kinetics in the aqueous-phase Suzuki reaction of aryl bromides and chlorides at relatively mild conditions (1 h at 50 degrees C). The GO-NHC-Pd catalyst was reused several times without any loss of its catalytic activity in the Suzuki reaction of aryl bromide. (C) 2014 Elsevier Ltd. All rights reserved.