• 文献标题:   Three-dimensional sulphur/nitrogen co-doped reduced graphene oxide as high-performance supercapacitor binder-free electrodes
  • 文献类型:   Article
  • 作  者:   HUO JH, ZHENG P, WANG XF, GUO SW
  • 作者关键词:   reduced graphene oxide, sulphur/nitrogen codoped, binderfree electrode, supercapacitor
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Shaanxi Univ Sci Technol
  • 被引频次:   15
  • DOI:   10.1016/j.apsusc.2018.01.221
  • 出版年:   2018

▎ 摘  要

Sulphur/nitrogen co-doped reduced graphene oxide (SNG) aerogels were prepared by a simple solvothermal method with l-cysteine-assisted in ethylene glycol. The morphology and composition tests showed that the S/N heteroatoms were evenly distributed on SNG microsheets, and these microsheets were further composed of SNG aerogels with three-dimensional (3D) porous structure. The cyclic voltammetry and galvanostatic charge/discharge tests illustrated the SNG bind-free electrode possessed electric double-layer capacitance and pseudocapacitance, and had a capacitance of 254 F g(-1) at a current density of 1 A g(-1). After the 5000 cycles tests, the capacitance retained 83.54% at a current density of 2 A g(-1). Meanwhile, the electrochemical impedance spectroscopy data shown the electrode materials had excellent capacity and good conductivity. Hence, the SNG aerogel prepared by l-cysteine-assisted solvothermal method is a great material for high-performance supercapacitors. (C) 2018 Elsevier B.V. All rights reserved.