• 文献标题:   Ex-MWNTs: Graphene Sheets and Ribbons Produced by Lithium Intercalation and Exfoliation of Carbon Nanotubes
  • 文献类型:   Article
  • 作  者:   CANOMARQUEZ AG, RODRIGUEZMACIAS FJ, CAMPOSDELGADO J, ESPINOSAGONZALEZ CG, TRISTANLOPEZ F, RAMIREZGONZALEZ D, CULLEN DA, SMITH DJ, TERRONES M, VEGACANTU YI
  • 作者关键词:  
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   IPICYT
  • 被引频次:   269
  • DOI:   10.1021/nl803585s
  • 出版年:   2009

▎ 摘  要

We found that multiwalled carbon nanotubes (MWNTs) can be opened longitudinally by intercalation of lithium and ammonia followed by exfoliation. Intercalation of open-ended tubes and exfoliation with acid treatment and abrupt heating provided the best results. The resulting material consists of: (i) multilayered flat graphitic structures (nanoribbons), (ii) partially open MWNTs, and (iii) graphene flakes. We called the completely unwrapped nanotubes ex-MWNTs, and their large number of edge atoms makes them attractive for many applications.