• 文献标题:   ZnO nanorods/Fe3O4-graphene oxide/metal-organic framework nanocomposite: recyclable and robust photocatalyst for degradation of pharmaceutical pollutants
  • 文献类型:   Article
  • 作  者:   CHEN L, PENG J, WANG FQ, LIU DH, MA WR, ZHANG JM, HU WQ, LI N, DRAMOU P, HE H
  • 作者关键词:   nanosized semiconductor, zif8, heterogeneous catalysi, scavenger, adsorption
  • 出版物名称:   ENVIRONMENTAL SCIENCE POLLUTION RESEARCH
  • ISSN:   0944-1344 EI 1614-7499
  • 通讯作者地址:  
  • 被引频次:   14
  • DOI:   10.1007/s11356-020-12253-2 EA JAN 2021
  • 出版年:   2021

▎ 摘  要

Nanosized semiconductors are widely utilized as solar energy based photocatalyst. However, the deficiencies such as poor adsorption toward contaminants and recyclability issues, rapid recombination of photo-introduced radicals, and deactivation by scavengers are still be the obstacle. To addressing those obstacles, zeolitic imidazolate framework-8 (ZIF-8), photosensitive ZnO, and paramagnetic Fe3O4 were anchored on conductive graphene oxide (GO) to prepare a nanocomposite photocatalyst ZnO/Fe3O4-GO/ZIF. The photocatalyst showed good robustness to scavengers of hydroxyl radicals (OH center dot), superoxide radicals (O-2(center dot-)), and hole (h(+)) with hydrophobic ZIF-8 modified surface. Finally, four pharmaceuticals (sulfamethazine, metronidazole, norfloxacin, and 4-acetaminophen) were degraded rapidly under simulated solar irradiation for 1 h, and the photocatalyst could be recycled at least ten times without obvious deactivation. The final results show that combination of semiconductor, graphene oxide and ZIF-8 is a good idea for construction of efficient photocatalyst. It offers new views in interface modification of nanomaterials, photocatalysis, and adsorption.