• 文献标题:   Nanocomposites of Graphene Oxide and Metal-Organic Frameworks
  • 文献类型:   Review
  • 作  者:   UFLYAND IE, NAUMKINA VN, ZHINZHILO VA
  • 作者关键词:   graphene oxide, metalorganic framework, nanocomposite, in situ synthesi, postsynthetic approach
  • 出版物名称:   RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • ISSN:   1070-4272 EI 1608-3296
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1134/S107042722111001X
  • 出版年:   2021

▎ 摘  要

The state of the art in the field of preparing nanocomposites of graphene oxide with metal-organic frameworks and of studying their structure and properties is discussed. The most efficient method for preparing such nanocomposites is in situ reaction of graphene oxide with precursors of metal-organic frameworks. Electrochemical, mechanochemical, and sonochemical synthesis methods for preparing the nanocomposites were also developed. The post-synthetic method involving preparation of the material from the graphene oxide and metal-organic frameworks prepared in advance is less widely used. The composites are characterized by a sandwich-like structure in which the crystal structure of the initial metal-organic framework is preserved. The composites show promise because of possible synergistic effects between the porous solid (controlled surface area, selectivity, catalytic activity, etc.) and graphene oxide (conductivity, light absorption, mechanical stability, etc.).