• 文献标题:   Sulfur-Functionalized Graphene Oxide by Epoxide Ring-Opening
  • 文献类型:   Article
  • 作  者:   THOMAS HR, MARSDEN AJ, WALKER M, WILSON NR, ROURKE JP
  • 作者关键词:   epoxide opening, gold nanoparticle, graphene, graphene oxide, thiol
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Univ Warwick
  • 被引频次:   66
  • DOI:   10.1002/anie.201404002
  • 出版年:   2014

▎ 摘  要

The treatment of graphene oxide (GO) with potassium thioacetate followed by an aqueous work-up yields a new material via the ring-opening of the epoxide groups. The new material is a thiol-functionalized GO (GO-SH) which is able to undergo further functionalization. Reaction with butyl bromide gives another new material, GO-SBu, which shows significantly enhanced thermal stability compared to both GO and GO-SH. The thiol-functionalized GO material showed a high affinity for gold, as demonstrated by the selective deposition of a high density of gold nanoparticles.