• 文献标题:   Multilayer Epitaxial Graphene on Silicon Carbide: A Stable Working Electrode for Seawater Samples Spiked with Environmental Contaminants
  • 文献类型:   Article
  • 作  者:   SHRIVERLAKE LC, MYERSWARD RL, DEAN SN, ERICKSON JS, STENGER DA, TRAMMELL SA
  • 作者关键词:   multilayer epitaxial graphene, cyclic square wave voltammetry, seawater, identification algorithm, machine learning
  • 出版物名称:   SENSORS
  • ISSN:  
  • 通讯作者地址:   US Naval Res Lab
  • 被引频次:   0
  • DOI:   10.3390/s20144006
  • 出版年:   2020

▎ 摘  要

The electrochemical response of multilayer epitaxial graphene electrodes on silicon carbide substrates was studied for use as an electrochemical sensor for seawater samples spiked with environmental contaminants using cyclic square wave voltammetry. Results indicate that these graphene working electrodes are more robust and have lower background current than either screen-printed carbon or edge-plane graphite in seawater. Identification algorithms developed using machine learning techniques are described for several heavy metals, herbicides, pesticides, and industrial compounds. Dose-response curves provide a basis for quantitative analysis.