• 文献标题:   Self-assembly sandwich-like Fe, Co, or Ni nanoparticles/reduced graphene oxide composites with excellent microwave absorption performance
  • 文献类型:   Article
  • 作  者:   LI WX, LIU YY, GUO F, DU YE, CHEN YQ
  • 作者关键词:   reduced graphene oxide, sandwich structure, impedance matching, magnetic metal nanoparticle, microwave absorption performance
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:  
  • 被引频次:   35
  • DOI:   10.1016/j.apsusc.2021.150212 EA MAY 2021
  • 出版年:   2021

▎ 摘  要

The application of graphene-based composites as microwave absorbing materials still has some problems despite optimistic outlook. In this work, sandwich-like Fe, Co, or Ni nanoparticles/reduced graphene oxide (RGO) composites were successfully fabricated via self-assembly and thermal reduction techniques. The characterization results of XRD, Raman spectroscopy, XPS, SEM, TEM, and thermogravimetric analysis showed that the Fe, Co, and Ni nanoparticles were wrapped by flexible RGO nanosheets, showing sandwich structure. Moreover, the loading amounts of Fe, Co, and Ni nanoparticles were further controlled in a wide range. As expected, this unique sandwich structure can not only reduce the agglomeration of magnetic metal nanoparticles and RGO nanosheets, but also improve the impedance matching and the relaxation loss, achieving an attractive microwave absorption performance. For Co/RGO composites, the value of the minimum reflection loss is -50.60 dB, and the effective absorption bandwidth (RL < -10 dB) can cover the entire X-band and Ku-band with a low filling ratio of 25%. Moreover, the synthesis process is simple and does not require complicated equipment and a variety of chemical reagents, which are suitable for large-scale production and possible industrial applications. The present work provides a good design and fabricating avenue for new graphene-based nanocomposites.