• 文献标题:   Long cycling life of Li2MnSiO4 lithium battery cathodes under the double protection from carbon coating and graphene network
  • 文献类型:   Article
  • 作  者:   ZHAO Y, WU CX, LI JX, GUAN LH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   39
  • DOI:   10.1039/c3ta01521a
  • 出版年:   2013

▎ 摘  要

Li2MnSiO4 possesses a high theoretical capacity of 332 mA h g(-1) as a lithium battery cathode, but it suffered from rapid capacity fading due to the structural instability and manganese dissolution during cycles. Herein, we developed a unique reduced graphene oxide (RGO)@Li2MnSiO4@C composite as a cathode material for lithium ion batteries. Under the double protection from RGO and carbon coating, Li2MnSiO4 demonstrated outstanding electrochemical performance with a high capacity of 290 mA h g(-1) at 0.05 C, and a long cycling life up to 700 cycles at 1 C.