• 文献标题:   Effect of thermal reduction temperature on the electrochemical performance of reduced graphene oxide/MnO2 composites
  • 文献类型:   Article
  • 作  者:   WANG LY, WANG Y, ZHANG HX, WANG XM
  • 作者关键词:   rgo/mno2 composite material, specific capacitance, thermal reduction, functional group
  • 出版物名称:   NEW CARBON MATERIALS
  • ISSN:   1007-8827 EI 1872-5805
  • 通讯作者地址:   Taiyuan Univ Technol
  • 被引频次:   6
  • DOI:   10.1016/S1872-5805(15)60175-5
  • 出版年:   2015

▎ 摘  要

Thermally reduced graphene oxide (RGO)/MnO2, composites were prepared by the thermal reduction of graphene. oxide (GO)/MnO2, composites. The structure, electrical conductivity and specific capacitance of the composites before and after thermal reduction were investigated by SEM, XRD, FT-IR, the four-pointprobe method and cyclic voltammetry. Results showed that the GO and RGO significantly decreased the agglomeration of MnO2. The RGO/MnO2 composites had higher specific capacitances than pure MnO2, or GO/MnO2 composites. A RGO/MnO2 composite reduced at 600 degrees C had the highest specific capacitance of 321 F . g(-1) and good stability upon cycling. The presence of an optimum reduction temperature could be accounted for by the fact that the thermal reduction decreased the amount of oxygen-containing functional groups that contribute to pseudocapacitance in GO and increased its electrical conductivity which favors a capacitance increase.