• 文献标题:   Fabrication of Graphene Nanoplatelet/Epoxy Nanocomposites for Lightweight and High-Strength Structural Applications
  • 文献类型:   Article
  • 作  者:   KIM J, CHA J, JUN GH, YOO SC, RYU S, HONG SH
  • 作者关键词:   functionalization, graphene nanoplatelet, halpintsai model, mechanical propertie, polymer matrix nanocomposite
  • 出版物名称:   PARTICLE PARTICLE SYSTEMS CHARACTERIZATION
  • ISSN:   0934-0866 EI 1521-4117
  • 通讯作者地址:   Korea Adv Inst Sci Technol
  • 被引频次:   2
  • DOI:   10.1002/ppsc.201700412
  • 出版年:   2018

▎ 摘  要

Graphene nanoplatelets (GNPs), the most important mass-produced graphene, are fabricated as a mechanical reinforcement for epoxy matrix nanocomposites. Current performance of GNPs as a reinforcing filler is limited by their agglomeration and weak interfacial interaction with certain polymer matrices. Herein, an approach to produce noncovalently functionalized GNPs (F-GNPs) is reported that can be extended to the industrial level of mass production. The one-step functionalization process uses melamine, a low-cost chemical, to improve the interfacial adhesion and dispersion in an epoxy matrix. The mechanical properties of nanocomposites prepared with the F-GNP flakes are much better (94.3% and 35.3% enhancements in Young's modulus and tensile strength, respectively) than those of the unfilled pure epoxy. Experimental data are analyzed using the Halpin-Tsai model. The fabrication process developed in this paper provides a strategy to use GNPs at the industrial level in lightweight and high-strength structural applications.