• 文献标题:   Effect of reducing system on capacitive behavior of reduced graphene oxide film: Application for supercapacitor
  • 文献类型:   Article
  • 作  者:   AKBI H, YU L, WANG B, LIU Q, WANG J, LIU JY, SONG DL, SUN YB, LIU LH
  • 作者关键词:   capacitive behavior, reducing system, reduced graphene oxide film, dropcasting technique
  • 出版物名称:   JOURNAL OF SOLID STATE CHEMISTRY
  • ISSN:   0022-4596 EI 1095-726X
  • 通讯作者地址:   Harbin Engn Univ
  • 被引频次:   5
  • DOI:   10.1016/j.jssc.2014.10.004
  • 出版年:   2015

▎ 摘  要

To determine the best chemical reduction of graphene oxide film with hydriodic acid that gives maximum energy and power density, we studied the effect of two reducing systems, hydriodic acid/ water and hydriodic acid/acetic acid, on the morphology and electrochemical features of reduced graphene oxide film. Using acetic acid as solvent results in high electrical conductivity (5195 S m(-1)), excellent specific capacitance (384 F g(-1)) and good cyclic stability (about 98% of its initial response after 4000 cycles). Using water as a solvent, results in an ideal capacitive behavior and excellent cyclic stability (about 6% increase of its initial response after 2100 cycles). (C) 2014 Elsevier Inc. All rights reserved.