• 文献标题:   Batch equilibrium and kinetics of mercury removal from aqueous solutions using polythiophene/graphene oxide nanocomposite
  • 文献类型:   Article
  • 作  者:   MULIWA AM, ONYANGO MS, MAITY A, OCHIENG A
  • 作者关键词:   adsorption, graphene oxide, mercury, nanocomposite, polythiophene
  • 出版物名称:   WATER SCIENCE TECHNOLOGY
  • ISSN:   0273-1223 EI 1996-9732
  • 通讯作者地址:   Tshwane Univ Technol
  • 被引频次:   6
  • DOI:   10.2166/wst.2017.165
  • 出版年:   2017

▎ 摘  要

Polythiophene/graphene oxide (PTh/GO) nanocomposite (NC) was prepared through polymerisation of thiophene in the presence of GO and was used for mercury ions (Hg2+) adsorption in aqueous solutions. Equilibrium studies showed that mercury removal was strongly influenced by solution pH and GO composition in the NC. The equilibrium data were well described by both Langmuir and Freundlich isotherm models, with a Langmuir maximum adsorption capacity of 113.6 mg/g. Adsorption kinetics were rapid and correlated well with the pseudo-second-order model. The thermodynamic studies indicated that the adsorption was spontaneous and endothermic in nature, and occurred through a physicochemical mechanism. Desorption studies revealed that PTh/GO NC could be used repeatedly for three adsorption-desorption cycles without a significant loss in its capacity. Competing ions reduced mercury uptake although considerable values were still attained. The findings of this study suggest that PTh/GO NC is a potential adsorbent for Hg2+ removal from aqueous solutions.