• 文献标题:   Three-Dimensional Reduced Graphene Hydrogels Using Various Carbohydrates for High Performance Supercapacitors
  • 文献类型:   Article
  • 作  者:   ZHANG JL, XING LB, LIU TZ, QIN K, ZHOU J, CUI HY, ZHUO SP, SI WJ
  • 作者关键词:   carbohydrate, graphene, reduced graphene hydrogel, supercapacitor
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Shandong Univ Technol
  • 被引频次:   2
  • DOI:   10.1166/jnn.2017.12621
  • 出版年:   2017

▎ 摘  要

In present work, three-dimensional (3D) reduced graphene hydrogels (RGHs) are prepared through an efficient and facile strategy by employing three types of carbohydrates (glucose, fructose and sucrose) as reducing agents in aqueous solution of graphene oxide (GO) with ammonia. The formation of RGHs could be confirmed by X-ray powder diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FT-IR). The structures and porosity were characterized by field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM) and N-2 sorption experiments. Benefiting from the abundant porous architectures as fast ionic channels for electrochemical energy storage, the prepared RGHs exhibited a high specific capacitance up to 153.5, 145.0 and 150.3 F g(-1) at 0.3 A g(-1) for FRGHs (fructose), GRGHs (glucose) and SRGHs (sucrose), which can be maintained for 61.4, 61.5 and 46.9% as the discharging current density was increased up to 20 A g-1. Moreover, it also showed that the electrode based on RGHs has good electrochemical stability and high degree of reversibility in the charge/discharge cycling test.