• 文献标题:   Preparation and characterization of Fe3O4/graphene nanocomposite and investigation of its adsorption performance for aniline and p-chloroaniline
  • 文献类型:   Article
  • 作  者:   CHANG YP, REN CL, QU JC, CHEN XG
  • 作者关键词:   fe3o4/graphene nanocomposite, aniline removal, pchloroaniline removal, adsorption kinetic, adsorption isotherm
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Lanzhou Univ
  • 被引频次:   105
  • DOI:   10.1016/j.apsusc.2012.08.045
  • 出版年:   2012

▎ 摘  要

In the present study, Fe3O4/graphene nanocomposite was prepared by solvothermal method and characterized by transmission electron microscope, Fourier transform infrared spectrometer and vibration sample magnetometer. Effects of different factors, including initial solution pH, agitation time and adsorbate concentration, on adsorption capacity of Fe3O4/graphene nanocomposite for aniline and p-chloroaniline were investigated. Experimental results demonstrated aniline and p-chloroaniline could be effectively removed from aqueous solution by Fe3O4/graphene nanocomposite within 60 min without adjusting solution pH. The adsorption of aniline and p-chloroaniline onto Fe3O4/graphene nanocomposite obeyed pseudo-second-order kinetic model and Freundlich isotherm model. The saturation magnetization of the Fe3O4/graphene nanocomposite was about 120 emu g(-1), which ensured the convenient magnetic separation after adsorption. (C) 2012 Elsevier B. V. All rights reserved.