• 文献标题:   Synthesis and electrochemical performance of LiNi0.6Co0.2Mn0.2O2/reduced graphene oxide cathode materials for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   YUE P, WANG ZX, ZHANG Q, YAN GC, GUO HJ, LI XH
  • 作者关键词:   lithiumion batterie, composite material, reduced graphene oxide, spraydrying method, electrochemical performance
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   8
  • DOI:   10.1007/s11581-013-0873-6
  • 出版年:   2013

▎ 摘  要

A LiNi0.6Co0.2Mn0.2O2/reduced graphene oxide (RGO) composite with RGO content of 1.2 % was prepared by a simple spray-drying method instead of high-energy ball milling method. The composite has been characterized by X-ray diffraction, scanning electron microscope, transmission electron microscopy, energy dispersive spectroscopy, and charge/discharge test. The X-ray diffractometry result showed that composite possessed a typical hexagonal structure. The RGO sheets served as efficient electronically conductive frameworks benefitting from its 2D structure and outstanding electronic conductivity. The scanning electron microscope and transmission electron microscopy verified that LiNi0.6Co0.2Mn0.2O2 particles were wrapped with RGO sheets, which facilitated electronic conductivity between particles. The electrochemical results indicated that composite delivered a higher discharge capacity at various discharge rates. The cycling performance was also evaluated. The composite exhibited better cycling performance than pristine sample. Electrochemical impedance spectroscopy showed that the RGO can greatly reduce the charge transfer resistance. The results here gave clear evidence of RGO to improve electrochemical performance.