• 文献标题:   Nanostructured cation disordered Li2FeTiO4/graphene composite as high capacity cathode for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   YANG M, ZHAO XY, YAO C, KONG Y, MA LQ, SHEN XD
  • 作者关键词:   li2fetio4 material, cation disordered, nanostructure, lithiumion batterie
  • 出版物名称:   MATERIALS TECHNOLOGY
  • ISSN:   1066-7857 EI 1753-5557
  • 通讯作者地址:   Nanjing Tech Univ
  • 被引频次:   9
  • DOI:   10.1080/10667857.2016.1192372
  • 出版年:   2016

▎ 摘  要

Nanostructured Li2FeTiO4/graphene composite with a cation disordered rock salt structure (Fm-3m) has been synthesised via a solgel process using graphene oxide (GO) as a template. The as-prepared Li2FeTiO4 nanoparticles with a particle size of 20-50nm are uniformly distributed on the graphene substrate. The Li2FeTiO4/graphene cathode shows phase transformations of Fe2+/Fe3+ and Fe3+/Fe4+ in a wide potential range from 1.5 to 5.0V and possesses a high discharge capacity of 218.6 mAh g(-1) (equivalent to 1.4 Li per formula unit). A reversible capacity of 176.9 mAh g(-1) is maintained after 50 cycles. High capacity retention rate at 1C after 200 cycles is obtained. The Li2FeTiO4/graphene should be of great interest as a potential cathode material for high-performance lithium-ion batteries.