• 文献标题:   Removal performance and mechanism of Fe3O4/graphene oxide as an efficient and recyclable adsorbent toward aqueous Hg(II)
  • 文献类型:   Article
  • 作  者:   BULIN C, LI B, ZHANG YH, ZHANG BW
  • 作者关键词:   fe3o4, graphene oxide, hg ii, adsorptive removal, adsorption mechanism, recyclable
  • 出版物名称:   RESEARCH ON CHEMICAL INTERMEDIATES
  • ISSN:   0922-6168 EI 1568-5675
  • 通讯作者地址:   Cent Iron Steel Res Inst
  • 被引频次:   0
  • DOI:   10.1007/s11164-020-04217-5 EA JUL 2020
  • 出版年:   2020

▎ 摘  要

Decontamination of aqueous heavy metal is a challenging task of environmental remediation. Herein, we demonstrated an adsorptive method for efficient removal of aqueous Hg(II) using a magnetic nanocomposite Fe3O4/graphene oxide (Fe3O4/GO). Adsorption of Hg(II) onto Fe3O4/GO equilibrated in 4 min, with the adsorption percent and quantity of 91.17% and 547.01 mg g(-1), respectively. Fe3O4/GO can be easily recovered from solution via magnetic separation for reuse, and retaining 73.5% of its original capacity after five consecutive cycles. The Temkin model and PSO model were most suitable for describing adsorption in equilibrium and non-equilibrium state, respectively. Both GO and Fe(3)O(4)adsorbed Hg(II) via donating electrons in oxygen atoms toward Hg(II). Moreover, GO made a major contribution, while Fe(3)O(4)made a minor one to adsorption. The facile preparation, high adsorption efficiency, easy recovery, and reusability may enable Fe3O4/GO to be a promising adsorbent for aqueous Hg(II).