• 文献标题:   Cu(II)-metformin immobilized on graphene oxide: an efficient and recyclable catalyst for the Beckmann rearrangement
  • 文献类型:   Article
  • 作  者:   HAMED AS, ALI EM
  • 作者关键词:   copper, graphene oxide, amide, oxime, beckmann rearrangement
  • 出版物名称:   RESEARCH ON CHEMICAL INTERMEDIATES
  • ISSN:   0922-6168 EI 1568-5675
  • 通讯作者地址:   Univ Fallujah
  • 被引频次:   0
  • DOI:   10.1007/s11164-019-03985-z
  • 出版年:   2020

▎ 摘  要

In this study, for the first time, the copper(II) nanoparticles (NPs) have been immobilized on metformin-functionalized graphene oxide and then its catalytic applications have been investigated in synthesis of amides from aldoximes (Beckmann rearrangement). The chemical structure of prepared catalyst has been characterized by various analyses like FT-IR, TGA, TEM, SEM, EDX, and ICP. All analyses confirm the successful and stable immobilization of copper NPs on functionalized graphene oxide. This synthesized heterogeneous nanocatalyst showed excellent catalytic activity with high product yields and short reaction times. Also, the suggested catalyst could be recycled ten times without a drastic decrease in its catalytic activity. Graphic abstract