• 文献标题:   Enhanced Mechanical and Thermal Properties of Biodegradable Poly(butylene succinate-co-adipate)/Graphene Oxide Nanocomposites via In Situ Polymerization
  • 文献类型:   Article
  • 作  者:   ZHOU WD, WANG XW, WANG PL, ZHANG W, JI JH
  • 作者关键词:   biodegradable, composite, mechanical propertie, thermal propertie
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   9
  • DOI:   10.1002/app.39512
  • 出版年:   2013

▎ 摘  要

Poly(butylene succinate-co-butylene adipate) (PBSA)/graphene oxide (GO) nanocomposites were synthesized via in situ polymerization for the first time. Atomic force microscopy demonstrated the achievement of a single layer of GO, and transmission electron microscopy proved the homogeneous distribution of GO in the PBSA matrix. Fourier transform infrared spectroscopy results showed the successful grafting of PBSA chains onto GO. With the incorporation of 1 wt % GO, the tensile strength and flexural modulus of the PBSA were enhanced by 50 and 27%, respectively. The thermal properties characterized by differential scanning calorimetry and thermogravimetric analysis showed increases in the melting temperatures, crystallization temperatures, and thermal stability. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 4075-4080, 2013