• 文献标题:   Fluorine-Doped Graphene/Nanosized Carbide-Derived Carbon Composites for High-Performance Supercapacitor
  • 文献类型:   Article
  • 作  者:   YAN PT, YAN L, ZHAO SM, ZUO Z, WANG XX, WANG CL, HOU ML
  • 作者关键词:   fluorinedoped graphene, carbidederived carbon, graphene composite, supercapacitor
  • 出版物名称:   NANO
  • ISSN:   1793-2920 EI 1793-7094
  • 通讯作者地址:   Xingtai Univ
  • 被引频次:   1
  • DOI:   10.1142/S1793292019500991
  • 出版年:   2019

▎ 摘  要

A graphene-based composite with high electrochemical performance for supercapacitor applications is fabricated by introducing nanoscale carbide-derived carbon (NCDC) into the fluorinedoped graphene (FG). The incorporation of fluorine can increase the specific capacitance of graphene by providing more pseudocapacitance, whereas the introduction of NCDC into the FG/NCDC composite offers high specific surface area (SSA) (up to 1317 m(2) g(-1)) and hierarchical pore structure, resulting in an enhanced electric double layer capacitance. Due to the synergistic effect of pseudocapacitance and electric double layer capacitance, the specific capacitance of FG/NCDC composite can reach 321 F g(-1) at a scan rate of 5 mV s(-1) in aqueous electrolyte. Notably, the specific capacitance of the FG/NCDC composite is very stable during long-term cyclic tests, with no significant degradation after 10,000 cycles. Due to its excellent supercapacitive performance, the FG/NCDC composite can be considered as a promising electrode material for high-performance supercapacitors.