• 文献标题:   Cerium(III) Ion Sensing Based on Graphene Quantum Dots Fluorescent Turn-Off
  • 文献类型:   Article
  • 作  者:   SALEHNIA F, FARIDBOD F, DEZFULI AS, GANJALI M, NOROUZI P
  • 作者关键词:   graphene quantumdot, ceriumion, fluorescence quenching, nanochemosensor
  • 出版物名称:   JOURNAL OF FLUORESCENCE
  • ISSN:   1053-0509 EI 1573-4994
  • 通讯作者地址:   Univ Tehran
  • 被引频次:   17
  • DOI:   10.1007/s10895-016-1962-5
  • 出版年:   2017

▎ 摘  要

In this work, graphene quantum dots (GQDs) was synthesized through hydrothermal method and used as a photoluminescent bulk nano-chemosensor for detection of Ce3+ ion in the aqueous solution. The synthesized GQD was characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), UV-Visible absorption and fluorescence emission spectroscopy. The sheet diameters of the synthesized GQDs were mainly distributed in the range of 15-20 nm. The interactions of GQDs with common cations and lanthanide ions were studied by fluorescence spectroscopy. Among the tested cations, Ce3+ ions was able to quench the fluorescence emission intensity of the GQD selectively. This quenching can be attributed to a redox mechanism between Ce3+ ion on the GQDs surface.