▎ 摘　　要

This paper describes a strategy for preparing free-standing reduced graphene oxide@Si nanoparticles (rGO@Si NPs) composite membranes. Graphene oxide (GO) was reduced and self-assembled synchronously with nanoparticles of silicon (Si NPs) on a metal surface and the composite film was subsequently used in a lithium-ion battery (LIB). This work describes several important novel aspects of the reported technology. Firstly, the composite membrane has a flexible self-supporting structure, allowing it to function as an anode material without requiring binders and current collectors. Secondly, the successful assembly of Si NPs and reduced Graphene oxide (rGO) sheets has enabled the production of the rGO@Si NPs composite film with high controllability and orderliness. Thirdly, the conductive nature of graphene has significantly decreased the resistivity while enhancing the electron transport capacity of the battery anode. Lastly, the robust and flexible structure of the graphene sheet has greatly mitigated the large volume variation in Si NPs during charging or discharging, resulting in the rGO@Si NPs composite film exhibiting excellent energy density and high-power density.