▎ 摘　　要

We develop here a simple wet chemistry to prepare covalent functionalized graphenes (FGs) through epoxide aminolysis especially under alkaline aqueous condition. Remarkably, a series of typical monoamines, such as industrial Huntsman JeffamineA (R) M-2070 and M-2005 polymer with hydrophilic or hydrophobic polyetheramine chains, positively-charged 2-amino-N,N,Ntrimethylpropanaminium, negatively-charged sulfanilic acid, even oligopeptide sequence, can be effectively grafted on the platelets of graphene oxide precursor with covalent functionalization and partially reduced features. This strategy provides the researchers a facile and convenient approach to design and synthesize solution processable, biocompatible and functionalized graphenes for the potent applications in electronic inks, drug carriers and biomedicines. Expansion of the current study is actively ongoing in our laboratory.