• 文献标题:   Polarized Raman spectroscopy with differing angles of laser incidence on single-layer graphene
  • 文献类型:   Article
  • 作  者:   HEO G, KIM YS, CHUN SH, SEONG MJ
  • 作者关键词:   graphene, polarized raman, oblique incidence, raman selection rule
  • 出版物名称:   NANOSCALE RESEARCH LETTERS
  • ISSN:   1931-7573 EI 1556-276X
  • 通讯作者地址:   Chung Ang Univ
  • 被引频次:   6
  • DOI:   10.1186/s11671-015-0743-4
  • 出版年:   2015

▎ 摘  要

Chemical vapor deposition (CVD)-grown single-layer graphene samples, transferred onto a transmission electron microscope (TEM) grid and onto a quartz plate, were studied using polarized Raman spectroscopy with differing angles of laser incidence (theta). Two different polarization configurations are used. In an in-plane configuration, the polarization direction of both incident and scattered light is parallel to the graphene plane. In an out-of-plane configuration, the angle between the polarization vector and the graphene plane is the same as the angle of laser incidence (theta). The normalized Raman intensity of the G-band measured in the out-of-plane configuration, with respect to that in the in-plane configuration, was analyzed as a function of theta. The normalized Raman intensity showed approximately cos(2) theta-dependence up to theta = 70 degrees, which can be explained by the fact that only the electric field component of the incident and the scattered photon in the out-of-plane configuration projected onto the graphene plane can contribute to the Raman scattering process because of the perfect confinement of the electrons to the graphene plane.