• 文献标题:   Rapid photo-degradation of 2-chlorophenol under visible light irradiation using cobalt oxide-loaded TiO2/reduced graphene oxide nanocomposite from aqueous media
  • 文献类型:   Article
  • 作  者:   SHARMA A, LEE BK
  • 作者关键词:   photocatalysi, 2chlorophenol, kinetic, regeneration, dopant
  • 出版物名称:   JOURNAL OF ENVIRONMENTAL MANAGEMENT
  • ISSN:   0301-4797 EI 1095-8630
  • 通讯作者地址:   Univ Ulsan
  • 被引频次:   31
  • DOI:   10.1016/j.jenvman.2015.09.013
  • 出版年:   2016

▎ 摘  要

The photocatalytic removal of 2-chlorophenol (2-CP) from water environment was investigated by TiO2-RGO-CoO. Cobalt oxide-loaded TiO2 (TiO2-CoO) supported with reduced graphene oxide (RGO) was synthesized using a sol gel method and then annealed at 500 degrees C for 5 min. The material characteristics were analyzed by UV-Vis analysis, Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) spectroscopy. Incorporation of cobalt oxide and RGO into the TiO2 system (TiO2-RGO-CoO) lowered the band gap energy to 2.83 eV, which greatly enhanced the visible light absorption. The TiO2-RGO-CoO photocatalyst showed complete removal of 20 mg/L. 2-CP within 8 h with the addition of 0.01% H2O2 under 100 W visible light irradiation. The photo-degradation efficiency of 2-CP (10 mg/L) was 35.2, 48.9, 58.9 and 98.2% for TiO2, TiO2-RGO, TiO2-CoO and TiO2-RGO-CoO, respectively, in the presence of visible light irradiation at solution pH of 6.0. The TiO2-RGO-CoO photocatalyst retained its high removal efficiency even after five photocatalytic cycles. (C) 2015 Elsevier Ltd. All rights reserved.