• 文献标题:   Sulphur doping: a facile approach to tune the electronic structure and optical properties of graphene quantum dots
  • 文献类型:   Article
  • 作  者:   LI XM, LAU SP, TANG LB, JI RB, YANG PZ
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Hong Kong Polytech Univ
  • 被引频次:   132
  • DOI:   10.1039/c4nr00693c
  • 出版年:   2014

▎ 摘  要

Sulphur-doped carbon-based materials have attracted a great deal of interest because of their important applications in the fields of oxygen reduction reactions, hydrogen storage, supercapacitors, photocatalysts and lithium ion batteries. Here, we report a new member of sulphur-doped carbon-based materials, i e. sulphur doped graphene quantum dots (S-GQDs). The S-GQDs were prepared by a hydrothermal method using fructose and sulphuric acid as source materials. Absorption and photoluminescence investigations show that inter-band crossings are responsible for the observed multiple emission peaks. The incorporation of similar to 1 at% of S into the quantum dots can effectively modify the electronic structure of the S-GQDs by introducing S-related energy levels between pi and pi* of C. The additional energy levels in the S-GQDs lead to efficient and multiple emission peaks.