• 文献标题:   Catalytic degradation of organic dye using reduced graphene oxide-polyoxometalate nanocomposite
  • 文献类型:   Article
  • 作  者:   UCAR A, FINDIK M, GUBBUK IH, KOCAK N, BINGOL H
  • 作者关键词:   graphene composite, polyoxometalate, catalytic degradation, methylene blue, rhodamine b
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   Selcuk Univ
  • 被引频次:   11
  • DOI:   10.1016/j.matchemphys.2017.04.047
  • 出版年:   2017

▎ 摘  要

Silicotungstic acid (SiW) decorated reduced graphene oxide (rGO) nanocomposite (rGO-SiW) has been prepared and evaluated as a heterogeneous nanocatalyst for the degradation reactions of methylene blue (MB) and rhodamine B (RhB). The structural and morphological properties of rGO-SiW nanocomposite were investigated by various techniques such as Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, X-ray diffraction (XRD), Atomic force microscopy (AFM) and Scanning electron microscope (SEM), which revealed the homogeneous and noncovalent anchoring of SiW nanoparticles on rGO sheets. The catalytic activity of rGO-SiW nanocomposite on the degradations of MB and RhB has been monitored using UV-visible absorption spectrometry in the presence of NaBH4 as the reducing agent at room temperature in water. The reduction reactions followed pseudo-first order kinetics and degradation were achieved in 34 min for MB and 81 min for RhB using rGO-SiW as catalysts. (C) 2017 Elsevier B.V. All rights reserved.