• 文献标题:   Raman Spectroscopic Characterization of Graphene
  • 文献类型:   Review
  • 作  者:   TANG B, HU GX, GAO HY
  • 作者关键词:   raman spectroscopy, graphene, doping, strain, fwhm
  • 出版物名称:   APPLIED SPECTROSCOPY REVIEWS
  • ISSN:   0570-4928 EI 1520-569X
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   112
  • DOI:   10.1080/05704928.2010.483886
  • 出版年:   2010

▎ 摘  要

The recent progress using Raman spectroscopy and imaging of graphene is reviewed. The intensity of the G band increases with increased graphene layers, and the shape of 2D band evolves into four peaks of bilayer graphene from a single peak of monolayer graphene. The G band will blue shift and become narrow with both electron and hole doping, whereas the 2D band will blue shift with hole doping and red shift with electron doping. Frequencies of the G and 2D band will downshift with increasing temperature. Under compressed strain, the upshift of the G and 2D bands can be found. Moreover, the strong Raman signal of monolayer graphene is explained by interference enhancement effect. As for epitaxial graphene, Raman spectroscopy can be used to identify the superior and inferior carrier mobility. The edge chirality of graphene can be determined by using polarized Raman spectroscopy. All results mentioned here are closely relevant to the basic theory of graphene and application in nanodevices.