• 文献标题:   Surface modification of graphene oxide by citric acid and its application as a heterogeneous nanocatalyst in organic condensation reaction
  • 文献类型:   Article
  • 作  者:   MALEKI A, HAJIZADEH Z, ABBASI H
  • 作者关键词:   graphene oxide, citric acid, heterogeneous catalyst, nanocomposite, imidazole
  • 出版物名称:   CARBON LETTERS
  • ISSN:   1976-4251 EI 2233-4998
  • 通讯作者地址:   Iran Univ Sci Technol
  • 被引频次:   9
  • DOI:   10.5714/CL.2018.27.042
  • 出版年:   2018

▎ 摘  要

A citric acid functionalized graphene oxide nanocomposite was successfully synthesized and the structure and morphology of the nanocatalyst were comprehensively characterized by Fourier transform infrared spectroscopy, energy-dispersive X-ray analysis, X-ray diffraction patterns, atomic force microscopy images, scanning electron microscopy images, transmission electron microscopy images, and thermogravimetric analysis. The application of this nanocatalyst was exemplified in an important condensation reaction to give imidazole derivatives in high yields and short reaction times at room temperature. The catalyst shows high catalytic activity and could be reused after simple work up and easy purification for at least six cycles without significant loss of activity, which indicates efficient immobilizing of citrate groups on the surface of graphene oxide sheets.