• 文献标题:   Reaction mechanism of Al-CuO nanothermites with addition of multilayer graphene
  • 文献类型:   Article
  • 作  者:   SHEN JP, QIAO ZQ, WANG J, YANG GC, CHEN J, LI ZQ, LIAO X, WANG HY, ZACHARIAH MR
  • 作者关键词:   multilayer graphene, alcuo nanothermite, cuoc reaction, alc bond, reaction mechanism
  • 出版物名称:   THERMOCHIMICA ACTA
  • ISSN:   0040-6031 EI 1872-762X
  • 通讯作者地址:   Nanjing Univ Sci Technol
  • 被引频次:   10
  • DOI:   10.1016/j.tca.2018.06.005
  • 出版年:   2018

▎ 摘  要

Reactions of nanothermites is complex, and the heterogeneous reaction poorly understood. In this study Al-CuO-multilayer graphene (MLG) composites were studied to explore the effects of MLG on the reaction properties, products composition and reaction mechanism of Al-CuO nanothermites. The morphology composition of Al-CuO-MLG composites before and after reaction was studied by scanning electron microscope (SEM). And detailed reaction pathways were characterized by X-ray diffraction (XRD), thermal gravimetric analysis and differential scanning calorimeter (TG-DSC) and X-ray photoelectron spectroscopy (XPS). Results indicate that the presence of MLG between nano-Al and nano-CuO particles tunes and improves reaction characteristics. A total heat of reaction of the Al-CuO-MLG (1 wt%) composites is 1679 J/g, increased by 87.5 J/g compared to that of Al-CuO composites.