▎ 摘　　要

The authors describe the application of two types of metallic foams modified with either graphene (GR) or carbon nanotubes (CNTs) as voltammetric electrodes in order to discriminate rice wines of different age and brand. Two types of bare metallic foams (bare Ni and Cu foam electrodes) were combined with GR or CNTs to give four types of modified metallic foams, referred to as GR/Ni, GR/Cu, CNT/Ni, and CNT/Cu foam electrodes. Cyclic voltammetry was applied to study the effects of GR and CNTs on the response of the electrodes. Multifrequency rectangle pulse voltammetry and multifrequency staircase pulse voltammetry were applied to generate potential waveforms, and chronoamperometric curves were recorded. Principal component analysis (PCA) allowed a classification of the rice wines, and characteristic regular distributions were identified in the PCA plots. Support vector machines (SVM) were found to perform better than partial least squares regression in predicting ages and brands of the rice wines in that all fit correlation coefficients were > 0.9930. The SVM based leave-one-out cross-validation method proved to be the most powerful regression tool. The six types of foam electrodes perform very well in the classification and prediction of rice wines of different ages and brands.