▎ 摘 要
We investigate the electronic physics of layered Ni-based trichalcogenide NiPX3 (X = S, Se), a member of transition metal trichalcogenides (TMTs) with the chemical formula ABX(3). These Ni-based TMTs distinguish themselves from other TMTs as their low energy electronic physics can be effectively described by the two e(g) d orbitals. The major band kinematics is characterized by the unusual long-range effective hopping between two third nearest-neighbor (TNN) Ni sites in the two-dimensional Ni honeycomb lattice so that the Ni lattice can be equivalently viewed as four weakly coupled honeycomb sublattices. Within each sublattice, the electronic physics is described by a strongly correlated two-orbital graphene-type model that results in an antiferromagnetic (AFM) ground state near half-filling. We show that the low energy physics in a paramagnetic state is determined by the eight Dirac cones which locate at K, K', K/2, and K'/2 points in the first Brillouin zone with a strong AFM fluctuation between two K (K') and K'/2 (K/2) Dirac cones and carrier doping can sufficiently suppress the long-range AFM order and allow other competing orders, such as superconductivity, to emerge. The material can be an ideal system to study many exotic phenomena emerged from strong electron-electron correlation, including a potential d +/- id superconducting state at high temperature.