• 文献标题:   One-step hydrothermal synthesis of 2D WO3 nanoplates@ graphene nanocomposite with superior anode performance for lithium ion battery
  • 文献类型:   Article
  • 作  者:   DANG W, WANG W, YANG Y, WANG Y, HUANG J, FANG X, WU LP, RONG ZH, CHEN X, LI X, HUANG LC, TANG XC
  • 作者关键词:   hydrothermal method, wo3 nanosheet@rgo, electrochemical performance, capacitive proces, lithiumion batterie
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   12
  • DOI:   10.1016/j.electacta.2019.04.184
  • 出版年:   2019

▎ 摘  要

The WO3 nanosheet@reduced graphene oxide (WO3 nanosheet@rGO) square particles have been synthesized successfully by a hydrothermal method. The structure and polymorphy of the particle are well characterized by XRD, FT-IR, XPS, SEM, TEM, HRTEM, Raman spectra and BET analysis. The electrochemical behaviors are researched by using CV, galvanostatic cycle and EIS. The results indicate that the special combination about the two-dimension WO3 nanoplate and graphene scales can promote the electrochemical properties of the metallic oxide effectively. Compared with the pure WO3, a higher initial discharge capacity of the WO3 nanosheet@rGO composite is 1143 mA h g(-1), the reversible capacity can also maintain in 1005.7 mA h g(-1) after 150 cycles in the condition of 100 mA g(-1) and 0.01-3 V. The outstanding electrochemical performances composite demonstrates that WO3 nanosheet@rGO synthesized by this method is feasible and could be used as a promising anode material for LIBs. (C) 2019 Elsevier Ltd. All rights reserved.