• 文献标题:   Graphene Monoxide Bilayer As a High-Performance on/off Switching Media for Nanoelectronics
  • 文献类型:   Article
  • 作  者:   WOO J, YUN KH, CHUNG YC
  • 作者关键词:   graphene monoxide, giant stark effect, band gap, electric field, firstprinciples calculation
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Hanyang Univ
  • 被引频次:   3
  • DOI:   10.1021/acsami.6b01772
  • 出版年:   2016

▎ 摘  要

The geometries and electronic characteristics of the graphene monoxide (GMO) bilayer are predicted via density functional theory (DFT) calculations. All the possible sequences of the GMO bilayer show the typical-interlayer bonding characteristics of two-dimensional bilayer systems with a weak van der Waals interaction. The band gap energies of the GMO bilayers are predicted to be adequate for electronic device application, indicating slightly smaller energy gaps (0.418-0.448 eV) compared to the energy gap of the monolayer (0.536 eV). Above all, in light of the band gap engineering, the band gap of the GMO bilayer responds to the external electric field sensitively. As a result, a semiconductor-metal transition occurs at a small critical electric field (E-C = 0.22-0.30 V/angstrom). It is therefore confirmed that the GMO bilayer is a strong candidate for nano electronics.