• 文献标题:   Harnessing the Liquid-Phase Exfoliation of Graphene Using Aliphatic Compounds: A Supramolecular Approach
  • 文献类型:   Article
  • 作  者:   CIESIELSKI A, HAAR S, EL GEMAYEL M, YANG HF, CLOUGH J, MELINTE G, GOBBI M, ORGIU E, NARDI MV, LIGORIO G, PALERMO V, KOCH N, ERSEN O, CASIRAGHI C, SAMORI P
  • 作者关键词:   electroactive material, graphene, liquidphase exfoliation, supramolecular chemistry
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Univ Strasbourg
  • 被引频次:   52
  • DOI:   10.1002/anie.201402696
  • 出版年:   2014

▎ 摘  要

The technological exploitation of the extraordinary properties of graphene relies on the ability to achieve full control over the production of a high-quality material and its processing by up-scalable approaches in order to fabricate large-area films with single-layer or a few atomic-layer thickness, which might be integrated in working devices. A simple method is reported for producing homogenous dispersions of unfunctionalized and non-oxidized graphene nanosheets in N-methyl- 2-pyrrolidone (NMP) by using simple molecular modules, which act as dispersion-stabilizing compounds during the liquid-phase exfoliation (LPE) process, leading to an increase in the concentration of graphene in dispersions. The LPE-processed graphene dispersion was shown to be a conductive ink. This approach opens up new avenues for the technological applications of this graphene ink as low-cost electrodes and conducting nanocomposite for electronics.