• 文献标题:   Radiation Enhancement by Graphene Oxide on Microelectromechanical System Emitters for Highly Selective Gas Sensing
  • 文献类型:   Article
  • 作  者:   LI NX, YUAN HY, XU LF, TAO JF, NG DKT, LEE LYT, CHEAM DD, ZENG YQ, QIANG B, WANG QJ, CAI H, SINGH N, ZHAO D
  • 作者关键词:   mems emitter, thermal emission, graphene oxide, radiation enhancement, infrared gas sensing
  • 出版物名称:   ACS SENSORS
  • ISSN:   2379-3694
  • 通讯作者地址:   Agcy Sci Technol Res
  • 被引频次:   6
  • DOI:   10.1021/acssensors.9b01275
  • 出版年:   2019

▎ 摘  要

Infrared gas sensors have been proven promising for broad applications in Internet of Things and Industrial Internet of Things. However, the lack of miniaturized light sources with good compatibility and tunable spectral features hinders their widespread utilization. Herein, a strategy is proposed to increase the radiated power from microelectromechanical-based thermal emitters by coating with graphene oxide (GO). The radiation can be substantially enhanced, which partially stems from the high emissivity of GO coating demonstrated by spectroscopic methods. Moreover, the sp(2) structure within GO may induce plasmons and thus couple with photons to produce blackbody radiation and/or new thermal emission sources. As a proof-of-concept demonstration, the GO-coated emitter is integrated into a multifunctional monitoring platform and evaluated for gas detection. The platform exhibits sensitive and highly selective detection toward CO2 at room temperature with a detection limit of 50 ppm and short response/recovery time, outperforming the state-of-the-art gas sensors. This study demonstrates the emission tailorability of thermal emitters and the feasibility of improving the associated gas sensing property, offering perspectives for designing and fabricating high-end optical sensors with cost-effectiveness and superior performance.