• 文献标题:   Purely Armchair or Partially Chiral: Noncontact Atomic Force Microscopy Characterization of Dibromo-Bianthryl-Based Graphene Nanoribbons Grown on Cu(111)
  • 文献类型:   Article
  • 作  者:   SANCHEZSANCHEZ C, DIENEL T, DENIZ O, RUFFIEUX P, BERGER R, PENG XL, MULLEN K, FASEL R
  • 作者关键词:   graphene nanoribbon, chiral, armchair, onsurface synthesi, bottomup, functionalized tip
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Swiss Fed Labs Mat Sci Technol
  • 被引频次:   51
  • DOI:   10.1021/acsnano.6b04025
  • 出版年:   2016

▎ 摘  要

We report on the atomic structure of graphene nanoribbons (GNRs) formed via on-surface synthesis from 10,10'-dibromo-9,9'-bianthryl (DBBA) precursors on Cu(111). By means of ultrahigh vacuum noncontact atomic force microscopy with CO-functionalized tips we unveil the chiral nature of the so-formed GNRs, a structure that has been under considerable debate. Furthermore, we prove that in this particular case the coupling selectivity usually introduced by halogen substitution is overruled by the structural and catalytic properties of the substrate. Specifically, we show that identical chiral GNRs are obtained from 9,9'-bianthryl, the unsubstituted sister molecule of DBBA.