• 文献标题:   High carrier mobility in graphene doped using a monolayer of tungsten oxyselenide
  • 文献类型:   Article
  • 作  者:   CHOI MS, NIPANE A, KIM BSY, ZIFFER ME, DATTA I, BORAH A, JUNG YH, KIM B, RHODES D, JINDAL A, LAMPORT ZA, LEE M, ZANGIABADI A, NAIR MN, TANIGUCHI T, WATANABE K, KYMISSIS I, PASUPATHY AN, LIPSON M, ZHU XY, YOO WJ, HONE J, TEHERANI JT
  • 作者关键词:  
  • 出版物名称:   NATURE ELECTRONICS
  • ISSN:   2520-1131
  • 通讯作者地址:  
  • 被引频次:   23
  • DOI:   10.1038/s41928-021-00657-y
  • 出版年:   2021

▎ 摘  要

Doped graphene could be of use in next-generation electronic and photonic devices. However, chemical doping cannot be precisely controlled in the material and leads to external disorder that diminishes carrier mobility and conductivity. Here we show that graphene can be efficiently doped using a monolayer of tungsten oxyselenide (TOS) that is created by oxidizing a monolayer of tungsten diselenide. When the TOS monolayer is in direct contact with graphene, a room-temperature mobility of 2,000 cm(2) V-1 s(-1) at a hole density of 3 x 10(13) cm(-2) is achieved. Hole density and mobility can also be controlled by inserting tungsten diselenide interlayers between TOS and graphene, where increasing the layers reduces the disorder. With four layers, a mobility value of around 24,000 cm(2) V-1 s(-1) is observed, approaching the limit set by acoustic phonon scattering, resulting in a sheet resistance below 50 omega sq(-1). To illustrate the potential of our approach, we show that TOS-doped graphene can be used as a transparent conductor in a near-infrared (1,550 nm) silicon nitride photonic waveguide and ring resonator. A monolayer of tungsten oxyselenide, created by oxidizing a layer of tungsten diselenide, can be used to efficiently dope graphene, leading to a room-temperature mobility of 2,000 cm(2) V-1 s(-1) at a hole density of 3 x 10(13) cm(-2).