• 文献标题:   Facile synthesis of graphene-wrapped CNT-MnO2 nanocomposites for asymmetric electrochemical capacitors
  • 文献类型:   Article
  • 作  者:   JIN EM, LIM JG, JEONG SM
  • 作者关键词:   asymmetric electrochemical capacitor, mno2, multiwalled carbon nanotube, graphene, electrical conductivity
  • 出版物名称:   JOURNAL OF INDUSTRIAL ENGINEERING CHEMISTRY
  • ISSN:   1226-086X EI 1876-794X
  • 通讯作者地址:   Chungbuk Natl Univ
  • 被引频次:   13
  • DOI:   10.1016/j.jiec.2017.06.022
  • 出版年:   2017

▎ 摘  要

CNT-MnO2 composites prepared by chemical redox deposition with various deposition times (0.5-2.0 h) were wrapped in functionalized graphene nanosheets (fGNSs) to improve their electrochemical pseudocapacitor properties. This treatment effectively improved the electrical conductivity and limited MnO2 loss during the charge-discharge process. The resulting fGNS-CNT-MnO2 (1 h) electrode exhibited the best pseudocapacitance of 202 F g(-1) and a cycling stability of 95%. In a two-electrode system with an activated carbon//fGNS-CNT-MnO2 asymmetric capacitor, the initial capacitance decreased by only 5% after 1000 cycles, and the corresponding power and energy densities were calculated to be 720W kg(-1) and 46 W h kg(-1), respectively, at 8 mA cm(-2). (C) 2017 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.